Oral Presentation 18th International Congress on Photobiology 2024

Effect of dose-delivery and exposed area on thymidine dimer excretion in urine. -A study in healthy volunteers (#208)

Catharina M Lerche 1 , Jonatan R Granborg 1 , Julie H Folman 1 , Amin Al-Haddad 1 , Stine R Wiegell 1 , Merete Haedersdal 1 , Hans Christian Wulf 1 , Peter A Philipsen 1
  1. Copenhagen University Hospital, Bispebjerg and Frederiksberg, Copenhagen NV, COPENHAGEN NV, Denmark

Introduction

Exposure of skin to solar ultraviolet radiation (UVR) induces the formation of thymidine dimers in DNA, serving as a biomarker for UVR exposure. Traditional analysis methods, like 32P-postlabeling, have been replaced by simpler LC-MS/MS techniques (1,2).

Aims

In this study, the impact of dose-delivery and exposed area on thymidine dimer excretion was investigated. Part 1 sought to determine if the administration of UVR dose influences thymidine dimer excretion by comparing the excretion after a single dose of 3 standard erythema doses (SED) with three doses of 1 SED given on consecutive days. Part 2 aimed to assess how the excretion of thymidine dimers is affected by the amount of clothing worn during exposure to 2 SED on 3 consecutive days.

Methods

Volunteers (n=16, part 1), (n=30, part 2) were exposed to UV6 tubes emitting 66% UVA and 34% UVB radiation. Morning urine samples were collected daily up to 8 days post-exposure and analyzed using LC-MS/MS. In Part 1, all volunteers were full body exposed. In Part 2, volunteers were divided into three groups with approximately 75%, 60%, or 45% exposed body surface area. Pigmentation and erythema values were measured using skin reflectance.

Results and Discussion

In Part 1 significantly higher levels of thymidine dimers were found in the group receiving a single dose of 3 SED compared to those receiving three doses of 1 SED (median 4325 ng vs. 730 ng, p=0.001). In Part 2, significant correlations were observed between thymidine dimers in urine and body surface area exposed (r2=0.20, p=0.012), as well as thymidine dimers and change in erythema (r2=0.38, p=0.00026).

Conclusion

In conclusion, receiving a single high dose of UVR results in higher thymidine dimer excretion compared to multiple lower doses. Additionally, there is a correlation between body surface area and excreted thymidine dimers in urine.

  1. 1) Lerche CM, Philipsen PA, Hermansson S, Heydenreich J and Wulf HC. Quantification of urinary thymidine dimers in volunteers after ultraviolet radiation using a new UPLC-MS/MS method. 2022. Anticancer Research 42: 5069-5076 doi:10.21873/anticanres.16015
  2. 2) Lerche CM, Frederiksen NSA, Thorsteinsson IS, Koester B, Nybo L, Flouris AD, Heydenreich J, Philipsen PA, Headersdal M, Wulf HC and Granborg J. Urinary thymidine dimer excretion reflects personal ultraviolet radiation exposure levels. Photochem and Photobiol Sci, 2024 (Accepted for publication)